i have the exact same problem..
i get this error when i go to Store > Settings > Payment Options > and then selecting a Payment Gateway from the drop down box (any option in the list)
using
– WordPress v3.0.1
– WP e-Commerce Plugin v3.7.7
– Gold Cart for WP e-Commerce v2.8
if there any solution to this? this is a pretty big issue i cannot set up my store with this error