For a temporary solution until your update comes I have disabled admin mails by modifying code.
File to be modified
wp-content/plugins/woocommerce-catalog-enquiry/classes/class-wc-Woocommerce-Catalog-Enquiry-ajax.php
Line no 67
$email_admin = get_option( 'admin_email' );
is to be replaced with
$email_admin = '';
@wolfram try this it will help till the update comes.