Hi,
Thanks for contacting us!
These two plugins are made by Brevo, although they contain different features.
The Newsletter, SMTP, Email marketing and Subscribe forms by Brevo (formely Sendinblue) plugin helps to create a form in order to collect emails addresses of subscribers.
You can find more information in this article : https://help.brevo.com/hc/en-us/articles/208849249-WordPress-plugin-Install-and-use-the-WordPress-plugin-for-Brevo
The Brevo for Woocommerce plugin is more related to ecommerce features. For example, you might be able to send some order confirmation emails or even order confirmation SMS.
You can find this tutorial here : https://help.brevo.com/hc/en-us/articles/209579245-WooCommerce-plugin-Installation-and-set-up
Do not hesitate to let me know if you need assistance.
Alexis