1. First you need to create a new options for that. You can do this by adding these lines of code inside options.php
file. Add it somewhere along other social icons.
$options[] = array( 'id' => 'social_vk',
'desc' => __('Vk.com', 'unite'),
'std' => '',
'class' => 'mini',
'type' => 'text');
2. Now that you have created an options you should create an output to make this icons visible. For that you should go to extras.php file and add this line:
$output .= unite_social_item(of_get_option('social_vk'), 'Vk.vom', 'vk');
You can add it right after this line of code:
$output .= unite_social_item(of_get_option('social_vimeo'), 'Vimeo', 'vimeo-square');
Now vk.com icon should be visible.
Let me know if this helpss