I want to change button ?

plugins\email-subscribers\widget\es-widget.css
You can modify the button style in the above mentioned CSS file.

@ gopi_plus,
Thanks you very much, because You have been my question.
I want to change word of button become submit. How do I this?

You can modify the text in the language file or you can modify directly in the below mentioned file.

plugins\email-subscribers\classes\es-loadwidget.php
Line number : 38

I tried to style the button by modifying the css you mentioned, but it does not work

original:
______________________

.es_textbox_button
{
width:100px;
}
______________________

.es_textbox_button
{
background-color:#ed8223;
color:#fff;
font-family:’Helvetica Neue’,sans-serif;
font-size:18px;
line-height:30px;
border-radius:20px;
-webkit-border-radius:20px;
-moz-border-radius:20px;
border:0;
text-shadow:#C17C3A 0 -1px 0;
width:120px;
height:32px
}