How do I integrate UPS so it prints automatically

Hi, I have WP 3.6 and woocommerce with the UPS plugin and I also have UPS Worldship on my computer with the UPS Zebra printer ZP450. I want to set up the system so when I get an order, it automatically prints a label. Maybe i am being too optimistic but I think that I will get far too many orders to even cut and paste let alone type the information. My website guy is gone, But I am fairly familiar with the back side of WP.There has got to be a way. I don’t see how the UPS plugin can export a XML which is what I think the worldship program needs. Thanks to all, hope you can help. Bob