This post isn’t clear, are you making a statement or asking a question?
If you send a message to a group of users all of the recipients will be placed in the BCC header. They will not be able to see who else received the message.
If you’re seeing different behavior, then something is changing the headers after WordPress is done processing it.
Email Users has a “debug” mode (it is on the plugin settings page – Dashboard->Settings->Email Users). When in debug mode, Email Users will output a bunch of information including the content of the mail headers to the Dashboard but IT WILL NOT actually send the email. This allows you to see the email which is constructed without actually sending it.