just go to your custom theme folder and open style.css file from wp-content/themes/yourtheme/style.css and in your case that is wp-content/themes/twentythirteen/style.css but the main problem is this if you do some change in style.css file in twentythirteen theme it will be lost when you update the WP so please make a child theme of twentythirteen and do your all the work in it.
1. replace body and site class like
body {
color: #141412;
line-height: 1.5;
margin: 0;
}
and
.site {
background-color: #fff;
border-left: 1px solid #f2f2f2;
border-right: 1px solid #f2f2f2;
margin: 0 auto;
max-width: 1600px;
width: 100%;
}
with
body {
color: #141412;
line-height: 1.5;
margin: 0;
background: red;
}
and
.site {
background-color: #fff;
border-left: 1px solid #f2f2f2;
border-right: 1px solid #f2f2f2;
margin: 0 auto;
max-width: 1600px;
width: 100%;
background: red;
}
i have added “background: red;” in both the code and if you want to change the color you can change it with hex code like #c5c5c5 or any other color code available on https://www.w3schools.com/cssref/css_colorsfull.asp. And you can also use image in backgound available on https://www.w3schools.com/css/css_background.asp