Hi there,
You could modify the e-mail template and use a custom code to according to your requirments. Here’s a good place to get started:
https://woocommerce.com/posts/how-to-customize-emails-in-woocommerce/
Also check this thread on how to add user role:
https://stackoverflow.com/questions/55479815/woocommerce-email-notifications-additional-recipients-based-on-user-role
https://stackoverflow.com/questions/51951837/how-to-add-wordpress-user-role-to-woocommerce-new-admin-order-email-subject
Please keep in mind, customizations and custom code like this falls outside the scope of our Support Policy and we’re unable to assist with it.
If you need help with development or customizations, I recommend taking a look at the services offered on our WooExperts page: https://woocommerce.com/experts/
You can also visit the WooCommerce Facebook group or the #developers channel of the WooCommerce Community Slack. We’re lucky to have a great community of open-source developers for WooCommerce, and many of our developers hang out there, as well.`
