Move Featured Image Below Title

Nope, not theme related; it’s all from the plugin.

You can move the title (name/title) above the avatar/featured image by placing the following code snippet in your theme functions.php:

add_filter( 'woothemes_our_team_item_template', 'new_team_member_template' );
function new_team_member_template( $tpl ) {
	$tpl = '<div itemscope itemtype="https://schema.org/Person" class="%%CLASS%%">%%TITLE%% %%AVATAR%% <div id="team-member-%%ID%%"  class="team-member-text" itemprop="description">%%TEXT%% %%AUTHOR%%</div></div>';
    return $tpl;
}

Great, thanks Amber worked a treat.